I basically had to format the 500GB from MBR to GPT. [AOMEI]
Create an EFI partition (size=100mb) on the 500GB. [diskpart]
Install Windows 10 on the 500GB, but still kept the files of course. [USB]
Wipe the 250GB. [diskpart]
Create a primary partition on the 250GB and assign a letter. [diskpart]
I have an SSD [C:] that came with a new laptop, and a separate SSD [E:] that contains all my files. I want to make the E: drive the primary boot drive. Both have Windows 10 installed on it.
I cannot do this through the BIOS so I'm assuming it has to do with where the Windows Boot Manager is...