cloning ssd

I have an Acer Aspire GX-785 circa 2016. It came with a 128Gb SSD drive, a 3TB HDD data drive and 16Gb DDR RAM and windows 10. The 128 drive is on the motherboard in an NVMe slot but seen as SATA Port 0. The 3Gb HDD is Port 3 and the Optical Disk is Port 5. Nothing is on Ports 2 or 4. For...