24-pin power was introduced to PC motherboards in anticipation of increased power demands, specifically for Intel's Prescott. Of course AMD boards have followed, Intel can push some things to the market.
The extra power pins are on the same rails as those that already exist on the 20-pin connector. Most boards simply group each rail too, so that many can't even tell whether you're using a 20-pin or 24-pin power supply.
But if you're interested in a new power supply anyway, I've prefered Fortron Source for years now, and lots of people like their 500W Blue Storm (although I'd just take a plain looking one myself).
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