Most 128 GB SSDs use half the number of flash dies internally as 256 GB SSDs. So the 256 GB is essentially two 128 GB SSDs in RAID-0 internally.
Setting up an external RAID-0 is mostly pointless on SSDs. Because it's external and because SSDs are so fast, the extra RAID overhead ends up slowing things down compared to running a single SSD at small file requests. RAID-0 does speed up large sequential file requests. But those aren't actually that common (outside a few tasks like real-time video editing), and represent only a small fraction of the time you spend waiting for your SSD to complete a read/write.
http://www.tomshardware.com/reviews/ssd-raid-benchmark,3485.html
tl;dr - get the 256 GB SSD.