Especially in Vista, the extra 1GB should help a lot, even w/o dual-channel mode. Depending on your specific CPU, dual-channel mode may be overkill, anyway. If you've got an Intel 800MHz FSB datarate CPU, DDR2-800 RAM is enough to saturate the FSB bandwidth even in single-channel mode.
However, you can have 3GB in dual-channel mode by installing 2x1GB + 2x512MB.