RAM modules are only guaranteed in the form sold (from the same pack). Even if they are the exact same make / model / timings, it is irrelevant. Mixed RAM modules are a 50/50 bet, sometimes it works, sometimes it doesn't. But there is no way you can ever guarantee compatiblity with mixed modules.
This usually is worse as the time of manufacture increases, as the module manufacturing process changes frequently. This is why it is always best practice to buy a whole new pack together when upgrading RAM.
So in short, will they work together if you buy just 1 more module and add them to your current? Maybe
Can anyone guarantee they'll work together? No.
You'll only be able to know if you try them, but frankly I'd say save the headache and potential conflict and just buy a new pack, because the last thing you'd want is pay money, to find out they won't work together.