Eps connects to the motherboard. It's a 4+4 pin connector.
Pcie connects to gpu. It's a 6 or 6+2 pin connector.
They are NOT the same, nor interchangeable or adapter-able. Any attempt to do so can fry gpu, motherboard, cpu, if psu protections (if it even has them) fail.
If your wanted gpu needs power, and your current psu does not have an available correct connector, it wasn't built to power that gpu.
Only correct solution is replace the psu with one correct for the application, with strong emphasis on a better quality, trusted psu, not an uber cheap yet high supposed output wattage unit.