The short answer, "no"
For the heat sink to be effective, it has to absorb the waste energy from the device. Any kind of barrier (most adhesives) will act as a heat shield. A reputable seller of "Heat Sink Kits" will include the heat conductive paste. just a dab, squished as thin as possible (minimizing the distance between the device and heat sink) will to the trick. In the squishing, you will have pushed out all of the air and the heat sink will adhere because of the vacuum created.
Clamping the heatsink to the device is the next thing to do.
OSD