The R9 should give the system a BIG boost, just bear in mind the CPU is an older gen part, and is clocked lower than the current mid/high end CPUs' so expect it, rather than the card, to struggle in some of the current CPU intensive games.
One last suggestion, but I think you've already looked into this: Consider the R9 270.
One last, last point: Again, I suspect you've already looked into this, but our (i5 750 in my rig) venerable CPUs can respond well to a little tickle with the overclocking stick...Just a thought. 😉