Asus P8Z68-V LE does not recognize all 32GB of RAM

First check if all those RAM sticks are working and are being recognized correctly in the First Slot of the Mobo.
Then if they are all fine, choose one stick and test all 4 Slots of the mobo to see that it shows up correctly.
This will make sure that none of the RAMs are faulty and none of the Slots are defective.