Try starting it up in "Safe Mode" and see if the charging still goes down or not. If it doesn't, then you likely have a software issue. Something is running on the laptop in normal mode that is causing it to lose power faster than it is being replaced.
However, if it continues to do this in "Safe Mode", then you could have gotten a bad charger, bad battery or it could be the motherboard.
Try charging when it is off (not sleep or hibernate but off) and see if it goes up. If it does, then that charger (new or not) may well be the problem.