The model of ram is meaningless. As is the brand. What is everything is the ram chips themselves. Ram is made from sheets of silicon, and every sheet has slightly different impurities as no silicon is 100% pure. It's those tiny amounts of impurities that affect everything. So you get the best compatibility from chips that come from the same sheet, and thats what is tested at the factory. If you buy a kit, the ram is almost guaranteed to be from the same sheet, usually sequential in serial number.
So if you buy singles, chances are better than very good that the ram itself is from a different sheet, even if you buy 2 sticks from the same store, same shelf, one next to the other, on the same day, at the same time.
Since Samsung and SkHynix both manufacture gskill products, and also manufacture Corsair, Patriot, and several dozen other 'brands', what you get is the same chips used by different brands and models, so your original stick that still works has exactly the same chances of compatibility with the new kit, as using a kit of Corsair LPX or Patriot Elite etc, which is to say it'll work, it'll work with adjustments or it doesn't work.
As far as using the old stick in flex, there's only one benefit, total ram size. All other conditions will either be moot or a detriment. The cpu will use the dual channel memory first, it has priority. It'll basically ignore the single channel ram as much as possible. The only time that ram will see any use is if the program that's run can actually make use of more ram, and would ordinarily saturate the dual channel amount, at which point the program slows down slightly as the cpu is also now dealing with single channel bandwidth as well as the dual channel bandwidth. That slowdown may not be as much as the possible slowdown if just the dual channel ram gets saturated, so would be an overall benefit to you.
You currently have 32Gb of ram in dual channel. I can't think of any game that can saturate 32Gb and would see a benefit to fps by the use of 48Gb in flex. Although it would be helpful in running multiple Virtual Machines or some production programs.