Not a good idea. Extending cables means voltage loss. Loss at the connector and loss over the length of the cable. As well as the mentioned cable mess to deal with. And of course dont forget the possibility of putting the pins in the wrong order(from someone who constantly wires connectors by hand, even if you have done it 1000 times, its easy to get distracted and accidentally do the pinout wrong, got to tripple check everything)
Voltage loss over the cable = more amps traveling over the cable to supply the same load = more heat in your case, and higher power bills(minor but still there).
Voltage loss if not regulated correctly will also potentially cause instability issues. If something expects 12 volts and you lose 0.5 volts on your cable you are only feeding 11.5, could easily push something out of spec. Voltage loss over 18 inches of 18 gauge copper wire at 10 amps is 0.19 volts(0.3 volts if aluminum), which isnt a lot, but we are already working with low voltages, and i could easily see it being a problem with some electronics.
If you really want looks, get the modular power supply and replace the entire cable.