Perhaps.
What is your motherboard?
CPU-Z will tell you.
In theory, one can add 4gb.
If it works, 2gb from each channel will operate in faster dual channel mode and the odd 2gb will be in slower single channel mode.
The operative consideration is "If it works"
Your odds of success are less than 100%
Ram is sold in kits for a reason.
A motherboard must manage all the ram using the same specs of voltage, cas and speed.
Ram from the same vendor and part number can be made up of differing manufacturing components over time.
Some motherboards can be very sensitive to this.
That is why ram vendors will NOT support ram that is not bought in one kit.
What will you do of you buy the ram and it does not work?
My suggestion is to go to a ram vendor like Kingston, corsair, g.skil and access their ram upgrade app.
Enter the make/model of your motherboard and you will get a list of supported kits.
Buy a kit of the capacity you need.
Keep the 2gb stick as a backup.