To CrossFire AMD branded video cards, both cards must have a graphics chip from the same family. So, if you wish to pair a second graphics card with your current HD 5670 you will need either an HD 5650 or HD 5670 graphics card to match it, as either of these cards are of the same family. When in CrossFire, both cards will run with the settings from the slower card.
It is recommended you have at least a 450 watt power supply or better if you wish to CrossFire a pair of HD 5670 graphics cards.
I would also recommend updating your graphics driver to the most recent for your system as AMD has made some great improvements to CrossFire support over the last year.