Before you go to lots of trouble is the disk system in your NAS even capable of using 1 2.5g port. Partially this is going to be based on the way you have the disk raid setup but it also greatly depends on the application and file structures. Generally the best speeds are going to be reading large single files.
You also must consider the machine on the other end talking to the nas it will be limited to 1gbit unless it too has faster ports.
In general you can not bond 2 ports together and get double the speed on a single file transfer. This is partially because of how the standard form of port aggregation chooses which path to send the data down. It select the path mathmatically based on ip and port numbers. So all traffic...