Short answer: No, you can't.
Explanation: Ohm's Law states that Voltage is directly proportional to Current and Resistance (V=IR). Watts is a measure of Voltage*Current (V*I). If you increase the number of Watts without changing the voltage or the resistance (which won't change since you're only using 1 circuit, your laptop), then the current will increase. The 65W charger won't be able to handle the higher current and will burn out.