There is no magic way to get more bandwidth from your ISP other than to pay them more money.
You have 3mbps total to share between the devices. To some small extent you can control which device gets how much bandwidth but that is a QoS function in your router not your switch. It also does not create more bandwidth it just decides who can use it. Even if you had a very advanced router that has very advanced QoS it does not work well on a small internet connection.
The only way a switch will increase you bandwidth is inside your house. You could for example hook up something like a security camera. The traffic between the security camera and some kind of DVR server would use the 100m ports on your switch to transfer data...