In order to take two physical raid groups (your SSD RAID and your 7200rpm RAID) and make a top level RAID with them, you need to do it on the software level.
So you would configure your raid for both disk groups through your on-board controller. Then you would need a third party program in windows to view both raid groups and make a third raid. The problems are many:
1) You can't boot from a software raid, because it requires being in a windows environment to work. So no nested RAID groups on boot drives.
2) Both VIRTUAL raid groups must be identical in size. You can't setup a RAID 1 between two disk groups that are different sizes. I imagine that your 7200rpm RAID0 is a different size that what your SSD RAID0 would be. Nested RAID follows the same rules of physical RAIDs.
Typically, in a high performance desktop, you want to design your storage like this:
Two disks or disk groups:
1st Disk group should be a fast, low capacity volatile group.
2nd Disk group should be a slow, high capacity, highly redundant group.
You would install windows, programs (like office, photoshop, etc) and games on the first group, then store your music, movies, pictures, game saves and other information on the second group.
For the first fast group, you would aim for a single SSD that maxes out your controller's speed (one 500MB/s or greater SSD or two SATAII SDD's in a RAID0 (Dont think that you can achieve theoretical SATAIII speeds in a RAID0. The speed is limited by the crappy on-board Marvell controller. You won't get >1GB/s speeds with an onboard controller by putting two vertex 3's in a RAID0, regardless of how many SATAIII ports and SSD's you have.
For the second disk group, aim for a couple of 2TB 7,200rpm drives in a RAID1. I know it's tempting to double your storage, but AVOID RAID0 on this disk group. Putting your second group in a RAID0 completely defeats the purpose of this design.
With this setup, you won't need to backup your primary group. All data on that group can be reinstalled if lost (and should be periodically for speed). Your second group can handle a hard drive failing, which should give you time to find a replacement and rebuild the raid before the other one fails.
Remember, if you buy two identical drives that are manufactured about the same time, expect them to fail about the same time as well. I manage a 64 disk SAN at work and I can say that once one fails, you should be expect the rest to fail shortly after.