I cant speak for the h100i, but the h110i is not controllable via BIOS or anywhere except Corsair Link because even though you plug it into the fan header, it only has a sense wire (third wire from left in the four pin cable) so the board knows there's a cooler attached, and you actually control the fans via USB. Try setting a custom fan curve in Corsair Link. I had to to reduce noise too, although ended up buying quieter fans as the stock ones sounded like a jet engine.
Puttibng the proifle to Quiet and setting a sensible fan curve is the best thing you can do. Also beware the fans respond to the pump temp not the cpu/system, so the curve will have to be v narrow, between 30-35c.