Well you could, but less your getting free USB sticks its unlikely to be cost effective.
At one point i asked a few companies to create "dust cover" usb 3 readyboost units, but none picked up on the idea, thou quite a few actually replied. Im thinking the readyboost tech has come and gone again, but i really just wanted tiny USB sticks with rounded/rubber heads to cover all those open plugs in laptops and boost performance a little.
Anyways to run a raid5 USB stick array and get decent performance, you would need them plugged in each their own USB port on the MB or an addon PCIe-USB3 card.
If you just build the array on a USB hub and superglue it all with a fan on top for good measure, your never going to get more than regular USB3 speed.
Anyways your not the only one who considered creative use of USB sticks, but i dont like your idea.