Not to worry.
80c. is a normal temperature for a graphics card under load.
Similarly, 70-85c. is not a problem for an intel chip under load.
Perhaps bothersome is why your liquid cooler is not doing better.
If it is mounted well and operating properly, I would expect to see 10-15c. over ambient at idle.
What is your case and fan arrangement?
Any cooler needs a source of fresh air to do it's job.
Do you do better with the case sides off?
he orientation of the radiator will cause a problem.
If you orient it to take in cool air from the outside, you will cool the cpu better, but the hot air then circulates inside the case heating up the graphics card and motherboard.
If you orient it to exhaust(which I think is better) , then your cpu cooling will be less effective because it uses pre heated case air.
Past that, A AIO radiator complicates creating a positive pressure filtered cooling setup which can keep your parts clean.