You mean expandable AIO? there're Swiftech H series, EKWB XLC Predator and Fractal Design Kelvin, those are mainly CPU water cooler with option for CPU + GPU watercooling depend on radiator size, usually 360 radiator is suffice for 350 watt TDP (i.e. 125 W CPU + 225 W GPU or two 175 W GPU).
The problem with two GPU AIO is
■ when there're no more room left to mount two radiators, such as NZXT Manta (two 240 mm radiator).
■ high end GPU overclocked TDP is over 200 W, makes push pull 140 radiator meet the cooling limit.
■ AIO pump was not design to coupe with other restriction point, you may hard mod AIO but the AIO pump's low flow rate and other water block pressure drop will slowly killing the cooled components.
SO DON'T , NEVER...