Yes you can, RAID 0 is essentially recognised as a single drive and so copying to a RAID volume is no different than a single hard drive.
The one thing to consider though is whether you are doing RAID using your motherboards RAID chipset or through drivers in windows. If its driver reliant you may have problems migrating windows without getting a BSOD since the appropriate drivers will not be installed. Your data will have been copied over in its entirety despite windows not working.
Either way, migrate your OS without deleting the original and see whether you can boot (you'll have a backup if anything goes wrong, practical application always gives you a definite answer).
Good luck, RAID 0 SSD's are awesome!