If you are building it based on the motherboard, with only four drives I would just buy a midtower case, low end i3 CPU using the onboard graphics and 4GB of memory (unless you are going with FreeNAS then more memory is useful).
If you go with Windows or Linux and need a true raid controller, an Adaptec 6405/7405/8405, or equivalent should work well unless you want room to grow, then get an 8 drive card like a 6805/7805/8805. Best to buy the cable with the card if they come bundled as they are cheaper. Of course, if you go with FreeNAS and use raidz you do not want a raid card, only a host bus adapter (the IBM M1015 is the best way to go for FreeNAS).
Buy good drives, enterprise quality for business data.
I have used that motherboard with an Adaptec 6805, so I know that it works even though some literature states the contrary.
Please correct any misunderstanding that I may have on your hardware, planned OS, or budget.