One of them needs to be the x1900xt Crossfire Edition card (aka a Master Card). You also need the crossfire DVI dongle that comes with the card. Basically, back in the day whe Crossfire first came out you needed a Master Card + a regular card OR (2) Master Cards. They used a dongle that plugged into the DVI out on one card and a special connector on the master card.
The cards now ALL have Crossfire built in and use a Crossfire bridge. Back in the day with the x1900's, you needed special cards. BLAH!, i know I had an x1900xtx and wanted to do this but the master cards were expensive and hard to find.
Looks like this.
http://intercomp.net.ru/Grafica/video/x1900_xtx/crossfire-on-mb.jpg