This is the best solution, if possible, according to various posts around the Internet, and I followed this advice for my build with Thermaltake Versa H17 that has only 1 mm of clearance margin left with the Peerless Assassin SE. Depending on your case size and RAM height, you may have enough clearance, more than what the case manufacturer claims. I have a small chassis, but had no problem raising the fan above the cooler block.
If you really have no choice but to move the fan from RAM facing to rear, I think you should not make it blow toward the cooling block, since it will interfere with the exhaust fan air flow and all other air flow. If the fan blow toward the exhaust fan, not sure it will help much. This means that the fan pulls air from the cooling block, which I suspect less effective. However, I'm not an expert in aerodynamics/thermodynamics so I might be wrong. Still, one thing I'm sure is that raising the first fan where it is supposed be is the best solution in your case.