CPU can be overclocked independently of RAM, so you won't get a higher OC because of better RAM. The difference is as you OC CPU, a higher DRAM Frequency will be a greater improvement. So to maximize performance in general, you want a high DRAM frequency like DDR3-2400. This is the typical upper range for the Haswell K CPUs.
Now whether you actually need to upgrade is dependent on your actual needs. Do you ever use 6-7GB? If that is common, you can consider 16GB DDR3-2400. If not, just stick with what you have and overclock it. That memory kit should handle 2133+ with higher timings and voltage. Also, I will be running a NH-D15 so I will have to remove the upper part of the heatsink. Will that be dangerous to do if I want to run it at 2400?
You don't want to get another two sticks. That can hinder performance because they are not a matched set. In some cases, they don't work at all, so if you plan to upgrade it's best to go with a complete 16GB kit.
Hope that helps, let us know how it goes! =)