OK, Chassis Fan is the mobo port you want to power a fan that cools the chassis. One is already in use - I expect for the pre-installed rear fan. Your new fan can plug into the other one. To chose the fan type, do NOT base it on the CPU fan port. Check the unused Chassis Fan port - is it 3-pin or 4-pin?
Yes, the spacing of mounting holes on a 120mm fan is standardized.
Let me clarify a bit better why the pin count on a fan makes a difference.
2-pin fan only gets its power from the two leads, and most often is connected somehow to a 4-pin Molex power output from the PSU. It can only run at full speed, unless it is connected to some other power supply.
3-pin fan has Ground (Pin 1, Black wire), +12 VDC varying (Pin 2, Red wire), and Speed Signal (Pin 3, Yellow wire). The mobo automatic control system changes the voltage on Pin 2 to achieve fan speed control. The speed signal on Pin 3 is generated inside the fan motor as a pulse train (2 pulses per revolution) and sent to the mobo for counting so the mobo can tell you the fan speed. But the speed is NOT controlled by this signal. The mobo changes the fan speed based on an actual measurement of TEMPERATURE of the device being cooled. This can be a temp signal from a sensor built into the CPU (for CPU cooling fan), OR a sensor built into the mobo for Case Fan control.
4-pin fan has those same first three pin signals, except that the +12 VDC line is always at +12 VDC. The wire color codes are different: Pin 1 (Grnd) Black, Pin 2 (+12 VDC) Yellow, Pin 3 (Speed pulses) Green, Pin 4 (PWM Signal) Blue. A few fans use different colors for Pins 2 and 3. The fourth pin's PWM Signal is used inside the fan motor by a small chip. The signal is a On / Off "square wave" type of signal with varying % On values, and it controls what percent of time the +12 VDC supply is actually fed to the fan, thus accomplishing fan speed control.
If you plug a 3-pin fan into a 3-pin fan port, or 4-pin into 4-pin, this all works. HOWEVER, you can mix them up with limited results. If you plug a 3-pin fan into a 4-pin port, it will run at full speed all the time because that is what a 4-pin fan port supplies - the +12 VDC line never has reduced voltage. If you plug a 4-pin fan into a 3-pin port, it will work fine, because the fan never gets a PWM signal to use, BUT it does receive a + voltage supply on Pin 2 that varies according the the mobo's control system. And yes, you can plug these things in that way - the fan pinout and physical structure allow that.
In general, the PWR_FAN port on a mob (IF there is one) is only for one purpose. It is intended for use when you have a PSU with a special set of wires coming out that terminate in what looks like a standard 3-pin fan connector. You plug this into the mobo PWR_FAN port, and it allows the fan inside the PSU to send its speed signal to the mobo for monitoring. The actual control of that PSU fan, if there is any, is done internally by the PSU itself - the mobo makes NO effort to control a fan attached to this port. However, some mobo makers have provided the Ground and +12VDC supplies on this port (voltage does not change), so you can plug in here a fan that will always run at full speed.
One additional suggestion, similar to what others have said in choosing a fan. I prefer to buy one that has ball bearings, rather than sleeve type. They last much longer before bearings wear out.