In your Windows Defender Firewall configuration are there any currently existing rules for Firefox?
Inbound, Outbound, Connection?
Monitoring Firewall?
My Windows Defender has a couple of existing rules in all categories.
Likely a Connection rule along with some Inbound or Outbound rule.
= = = =
If you run "nslookup bing.com" (without quotes do you get the following results?
PS C:\Users\XXXX> nslookup bing.com
Server: UnKnown
Address: 2601:147:c201:b20c:9610:3eff:fe00:3495
Non-authoritative answer:
Name: bing.com
Addresses: 2620:1ec:c11::200
13.107.21.200
204.79.197.200
Your requirement is clear and straightforward and I am finding it interesting that there does not seem to be some immediate "How To" tutorial.
Here is a link that may prove helpful....
http://woshub.com/block-domains-websites-windows-firewall-powershell/
My current thought is a Powershell script that blocks bing.com if Firefox is running.
Still that all seems to be a bit cumbersome in some ways. Do you have any sort of test environment to work in?