So the obvious but perhaps not most convenient option here would be to take advantage of the warranty if possible. Those temps are clearly not acceptable, although, it would be better to have some idea of what it's actually doing at the top end of the scale. Generally speaking the idle temperatures are mostly irrelevant EXCEPT when they are as high as yours are, and then it MIGHT indicate a problem. What matters most however is what happens under a full load.
Since it seems like you might not have a great deal of experience with the hardware side of things, as you are uncertain about the fans and what is what, it might really be a good idea to simply take advantage of the warranty or take it to a reputable repair facility that can take a look at your concerns for you. In truth, I think the problem is a poor case design rather than anything else and the fact that the AIO cooler is mounted in the secondary chamber without any form of intake fan whatsoever, as indicated by this review.
The Asus ROG GA35 is a compelling option with how hard graphics cards are to buy. It hits the mark for a high-end gaming PC, but it still has some issues.
www.digitaltrends.com
Since there is no place to mount any fans, and since the only exhaust fan is a single 92mm fan, which is about as crappy of a thermal design as you could come up with, I honestly think your very best option would be to get a real case and move everything into that, and then add a couple more fans. Probably this would cure your entire issue. Your AIO is trying to use hot air in the case and your tiny exhaust fan is just not capable of removing enough heat for it to even matter.