First, make sure that you've got your motherboard isolated from anything conductive. In the past I've measured the motherboard and put standoffs on a sheet of cardboard. Then just connect everything as usual.
Now you need some way to trigger the computer to start up. The easiest way to do this is to find the pins that the power switch from your front panel connects to (should be printed on the motherboard and/or listed in the manual) and then short the two pins with a screwdriver or jumper (this isn't very good for the motherboard). The best way would be to attach a 2-pin connector to a momentary-on switch and then connect that to the motherboard header (just like how it's done inside a case). After you hear the fan start up, make...