Not quite with you yet TheSpieler... perhaps I need to be clearer:
I have a current main machine (A) which has an ICH10 capable mb, but I am currently simply using it with 2x1tb disks in a raid0 config giving a 2tb partition.
Machine A is no longer viable as a high end gaming machine, and also it's high time I created a safe repository for all my data (I currently have no backup - yes yes yes I know - am flying close to the sun). Machine A will make a fine File Server/Web Server however (lets call this machine A2) and means I don't have to buy a new mb/processor/memory for A2 (the mb currently in machine A is only Sata 2 but the difference between Sata2 and Sata3 for my applications will not be significant). I will be using the new mb/proc/memory in a new gaming rig B, and once the data is safely on my raid5 I will wipe the raid0 and use that for the storage in B.
So current hardware:
mb
processor
memory
1xSSD (win7)
2x1tb disks in raid 0 (currently holding all data for the home network)
hardware that will be bought:
new mb/proc/memory
4x2tb disks which will form a 6Tb raid5
So the problem I have, and which prompted my question is that I want to set up the new raid5, and then copy what's on the raid0 to the raid5 - ergo all my lovely data is stored on the new, disk-fail-mitigated raid5. The trouble is, Jsc says that if I just move the two disks raid0 from A to B, there's a good chance the new mb wont be able to instantiate the raid0 properly and I'll lose my data.
So the end game is that I have a new raid5 in a machine which uses the current mb/proc/memory and a new spanky gaming rig with a 2tb raid0 for it's storage. And doing this hopefully without having to buy extra storage simply to do the migration.
Phew - hope thats clear. Thanks!