Your power supply only provides the power the components actually use. The power drawn from the wall socket is slightly higher, because the power supply is not 100% efficient (80-90% is pretty typical). So if your components draw 750W, your PC will actually draw around 830-940W from the wall.
Watt is the rate of energy use (Joules per second), so you can't say it uses 750 watts per second or per hour. It just uses 750W. Now, if you draw 750W for one second, that's 750 Joules of energy. If you draw 750W for an hour, that's 2.7 million Joule, or 0.75 kilowatt-hours.