You will need an additional device:
http://www.amazon.co.uk/eSynic%C2%AE-Digital-Optical-Coaxial-Converter/dp/B009ZR7IB8/ref=sr_1_1?s=electronics&ie=UTF8&qid=1424705174&sr=1-1&keywords=optical+to+rca
Your TV only outputs optical toslink and not RCA so you need that adapter box to downgrade the optical output to just analog stereo.
So your setup:
PS4 to TV via HDMI
TV to Adapter via optical toslink cable
Adapter to AMP via RCA cable
Amp to speakers via speaker cable
As far as what speaker cable just get some 16ga speaker cable. As much as Monster and others want you to believe that their $100 speaker cables are going to make a profound difference, they wont. The difference is in the thickness (gauge) of the wire, so get a 16 gauge and you are good
http://www.amazon.co.uk/AmazonBasics-16-Gauge-Speaker-Wire-Feet/dp/B006LW0W5Y/ref=sr_1_1?s=electronics&ie=UTF8&qid=1424705431&sr=1-1&keywords=16+gauge+speaker+wire