Hi
How did you get two windows installs?
If each hard disk has its own bootmanager partitions and possibly uefi partitions if using gpt partitioning then remove sata cables from the hard disk you think is spare and see if windows boots up properly
If it does it should be possible to remove windows, program files , program files (x86), program data once the hard disk is re connected
If not you need to get a windows 10 dvd or usb and try a repair of the windows startup system
It is possible windows on both hard disks share a startup system on one hard disk
Regards
Mike Barnes