OK let take on the other way, when u overclock a cpu, even if it starts and boot into OS why it is not stable? Because of the voltage on the junctions (or temperature but we presume that we got a kickass cooler). What do you do next, increase the voltage aka junction voltage and become stable, this applies to a cheap psu, the voltage on the 12V line is so low that the cpu is unstable (thats why the maximum drop on the 12V line is 0.3V). If a psu has a 12V at 11.3v or 11.5v then the cpu will suffer a lot(decrease in performance) because some junctions are closed.