verc00,
First and most relevant question; what is your Ambient temperature?
When you power up your rig from a cold start, all components are at Ambient, so temperatures can only go up. With conventional air or liquid cooling,
no temperatures can be less than or equal to Ambient, regardless of the CPU cooler.
Certain batches of Core i 6th Generation processors have been reported to have Digital Thermal Sensors (DTS) that were miscalibrated 10C too low, which show Core temperatures that idle below Ambient temperature. You might have one of theses processors.
CT