Sorry to hop in so late, and be the fly in the ointment, but you really need to figure out what PSU you have. Overclocking a chip that draws as much juice as yours requires a high quality power supply. A low quality unit, even if it can, on paper, provide the voltage, could be a serious, even fatal mistake for your system. Melt-down, literally. You've spent a lot of money on parts, make sure the PSU is up to it.
Now, here's the first question when somebody asks about temps and overclocking. Have you taken control of the voltage(meaning it's not on automatic control)?