I have a problem with a PC that does not start and there are several likely culprits, including motherboard and PSU. One way of looking for faults is to look for faulty or leaky capacitators, if they contain liquid electrolyte. However, all capacitors on these components are polymer-based (as far as I can see). Is there any way one can identify a failed polymer-based capacitor? I have been looking all over the net whithout finding clear advise on this, so any feedback would be much appreciated. Thanks 
The system in question:
Asrock X79 Extreme6, 64 GB, 1066, 1333, 1600, 1866, 2133, 2400 MHz, DDR3-SDRAM, quad, Intel, LGA2011 mainboard
Sapphire R9 280 Dual-X OC 3GB GDDR5 graphics card
Intel Socket 2011 - Intel Core I7-3820 3.60Ghz Box Socket 2011
Noctua NH-D14 SE2011 cooling
Corsair CMPSU-700G, 700 W, power
32 Gb memory
Be Quiet Shadow Wings 120mm 2200rpm fan
Win 7

The system in question:
Asrock X79 Extreme6, 64 GB, 1066, 1333, 1600, 1866, 2133, 2400 MHz, DDR3-SDRAM, quad, Intel, LGA2011 mainboard
Sapphire R9 280 Dual-X OC 3GB GDDR5 graphics card
Intel Socket 2011 - Intel Core I7-3820 3.60Ghz Box Socket 2011
Noctua NH-D14 SE2011 cooling
Corsair CMPSU-700G, 700 W, power
32 Gb memory
Be Quiet Shadow Wings 120mm 2200rpm fan
Win 7