This new PowerVia backside power delivery concept and it's success can be attributed to Nano-TSVs which are five-hundred times smaller than typical TSVs, as compared to previous backside power delivery concepts. This also allowed Intel to relax the pitch of the critical M0 metal layer, enlarging it from 30 nm to 36 nm.
So these deliver power straight to the M0 layer where the processing actually happens rather than having to pass through the M0 layer. It also doesn't have to account for extra power routing mucking up the signaling above the M0 layer.
However, Intel doesn’t offer a more detailed explanation as to why constructing an E-core with PowerVia technology improved the maximum frequency (fMax) of the core by 6%, though, I suspect it has to do with a higher voltage actually reaching the transistors themselves, allowing them to clock a bit higher.