FIRST, make sure you have the MOST up to date BIOS version installed. I cannot emphasize this enough. With memory issues, it is IMPERATIVE that you are up to date on the BIOS firmware. Make sure of this first.
Second, what PCPP shows or doesn't show is meaningless, almost entirely. The ONLY thing it shows is PHYSICAL compatibility, meaning either DDR3 or DDR4 that will physically fit the slot for a given generation of motherboard. It is in NO WAY meant to express "compatibility" with any given motherboard MODEL or CPU, although in some few cases you MIGHT see some memory modules not displayed due to incompatibility with a given CPU but it is unlikely on PCPP. PCPP compatibility is ONLY to determine that it is the right TYPE of memory, not that it is a model that is validated as compatible with your exact hardware configuration.
For that, you NEED to go to the memory manufacturers website and use their tool (G.Skill memory configurator, Corsair memory finder, Crucial memory advisor, etc.), which I am only aware of those three having a compatibility tool that offers actual validation verification on a board by board model basis. Beyond that you will be limited to the QVL list for the motherboard, which is only a small sampling of what is actually likely to work on any given board. For these reasons I tend to stay with those three memory manufacturers products (Not to mention because they are also the best in terms of quality, reliability and reputation) when selecting memory so I can validate compatibility prior to purchase and not waste a lot of time wondering if the memory I have is compatible or not.
The bigger issue, which is what many users run into, is that any time you add memory that did not come from the same kit, having been factory tested for compatibility, you are GREATLY increasing the probability that at some point (Whether immediately or at some later date) you will have compatibility issues between the separate kits and sticks, even if they are the exact same model.
Please read this for further clarification on that point:
https://forums.tomshardware.com/threads/amd-ram-compatibility.3210050/#post-19785792
That however is not likely (Although still possible, as some incompatible sticks within the kit occasionally make it through the brief testing validations. It happens, what can I say, same as other types of faulty products sometimes make it through the quality assurance process) since your memory seems to have all come in a single kit. Your problem MIGHT be the fact that that memory kit is NOT shown to be compatible (There are no G.Skill 3200mhz 4 x16GB kits that DO show compatibility with that board) on the G.Skill memory configurator tool. There are in fact no such kits showing compatibility with that board that consist of four DIMMs at 3200mhz, regardless of series or model, from G.Skill. In the past this has shown itself to be pretty accurate in terms of having problems with G.Skill memory on a given board if it does not show up in the configurator as compatible. It's true that it doesn't have to show as compatible to be able to BE compatible, and work normally, but OFTEN kits that don't show as compatible, aren't, and won't work without some kind of problems whether minor or major.
Also, Memtest86 is NOT always accurate. I've seen MANY memory kits that had problems but could pass Memtest, yet when replaced no further problems occurred. So that is usually the first option you want to look at if you are still within the window to return that memory kit OR you can contact G.Skill as they are usually very good about supporting their products especially if you can get into contact with one of their moderators on the G.Skill forum to assist you.
The other option and consideration is that you are running four DIMMs, and this OFTEN creates problems because it is a much less stable configuration on many dual channel architectures, and in some cases might require a minor boost in DRAM voltage beyond what the XMP profile sets it at. You can try increasing the memory voltage by increments of .005v (Or .020v if that is the increment your board allows), saving after each change and then retesting to see if the problem is eliminated during POST. If no improvement is seen by the time you've increased the DRAM voltage by several increments, then DRAM voltage is probably not the problem and before throwing in the towel on that memory kit, you might want to look into making some adjustments to the VCCIO and VCCSA voltages, both of which have relationships with the internal memory controller and can have an effect on systems, especially early DDR4 systems that didn't support higher memory speed operation nearly as well as newer platforms do, since the IMC is fundamentally involved in memory operations.
I would not recommend going higher than 1.1-1.2v, max, on either of these, unless you know exactly what you are doing and have educated yourself about these voltages to the best of the information that is available out there, for the average user. Those ranges should be safe but it is wise to look at professional reviews and guides for guidance on making these adjustments. This might be helpful as a starting point for doing that, but there is likely much more up to date information available elsewhere, potentially, given the age of the original guide.
https://www.tweaktown.com/guides/84...html#Intel-Max-Voltages-and-Stability-Testing