Arlen10 :
Eximo :
Usually one would do this in hardware, using the onboard RAID controller or a more specialized add in card.
Raid 0+1 is what you are looking for I believe. Two striped volumes mirrored to another striped set. I don't believe the mirrored volume absolutely has to be a matching set and can just be a large backup disk.
Your board does support RAID10 which is a bit different, but achieves your goal. This will mirror each drive in the striped array.
I won't be using my system for this. I'll be setting up a new computer for this. I know about RAID 10, I want to see if its possible to accomplish this with just spanning the drives in windows and setting up redundancy separately. Where the drives fill up 1 at a time rather than stripped evenly.
No RAID solution will fill up each drive 1 at a time. You either have performance, redundancy or a mix of both.
There is RAID 0+1 which will stripe two sets of two drives then make the second set a redundancy of the first set.
RAID 5 is striping with one parity bit (drive).
RAID 6 is the same as RAID 5 bit adds a second parity bit (drive) to the mix.
But no matter which you go for there will always be striping or redundancy and all drives will be used in some way unless it is a parity drive.