It's known that there is Zotac cards with 6xSP-CAP's in customers hands - not POSCAP's, cue AHOC rant about people getting this wrong, since he's very knowledgeable in this area and was showing the manufacturer's datasheets in the stream I'm going to assume he's right and the press is wrong on that.
EVGA's press release claims that they discovered the issue during testing in time to make sure no retail cards used 6 large caps, but that a few review samples did use this configuration and that they're working on getting those replaced. I'm fine with review samples having issues...
There's been rumors about a few other manufacturers but I'm not going to name any since I'm not sure on any of them.
And no, the MLC configuration definitely isn't cheaper. Yes, one MLC capacitors is likely cheaper than one large capacitor but the correct comparison is 10 MLC capacitors vs 1 larger capacitor and 10 MLC capacitors definitely cost more. The MLC configuration also takes slightly longer to make because there's more components for the picket machines to place - this is very small though because there's so many other components that even 54 extra doesn't add much percentage-wise.
When it comes to performance using 10 MLC instead of 1 large capacitor results in better performance in every way, so the reason for not use all MLC comes down to either cost or wanting to differentiate the more expensive cards - the improved filtering by the MLC array can lead to very slightly better overclocking capabilities (or possibly when it tries to boost very high in this case).
Note that as cards goes up the "stack" at one manufacturer they tend to get more MLCs and less of the large capacitors in the GPU back cavity which should show that using MLCs is the more expensive (and better) option.
The exception to all this appears to be ASUS - they appear to have gone with all-MLC on all of their 3080/3090 cards! Nice.