Rubbing alcohhol should be just fine.
No need to use the alcohol on the backplate, just wipe it dry.
When cleaning the circuit board do NOT wipe it, just dab the alcohol moistened Qtip/cotton bud/coffee filter gently onto the surface, alcohol is an astringent so it absorbs water and the cooling solution in your H80i is mainly water. Use several Qtips/cotton buds/coffee filters if you need to, changing it when it looks like you need to. Once the circuit board looks nice an clean leave it an hour or so to dry out fully before reinstalling the card.
You may not even need to clean the circuit board, if the leak is small, it my just be on the backplate.