You've got a few options, but none should involve a "RAID card" that fits in a PCIe x1 slot. That won't be a true RAID card and would have serious bandwidth limitations (only about 500MB/s to your mobo based on PCIe 2.0 which your mobo runs).
Option 1: You can connect your 2 x SSDs to your mobo's SATA ports and run RAID-1 on those two as your boot drive. Then purchase a 4 port dedicated RAID card for the other 4 drives. I recommend taking to ebay and find an LSI 9260-4i (4-port), 9260-8i (8-port), 9266-4i (1GB cache vs 9260's 512MB) or 9266-8i. Don't buy the OEM models (marked as Dell, IBM, etc). ONLY the actual LSI branded cards. I've bought the ones that come straight from China and they work like a charm.
Option 2: Buy one of those LSI cards & run all three arrays from it (8-port card required of course). Thing is, you don't want to use the cache on the RAID card for your SSD RAID so there's no reason to use the card for that array, except if your mobo fries you can forklift the RAID card and all the drives & just plug it in to another mobo & everything is still there like nothing happened.
You'll want/need to use your 2nd x16 slot for the dedicated RAID card. They all use 8 lanes from a PCIe slot.
In regards to the two RAID 1s for storage, if you haven't already got those drives (2 diff models), I would DEFINITELY do 4 x HDDs in a RAID-5 on the dedicated card with write-back enabled. If you have 4 x 1TB drives that will give you 3TB usable and read/write performance of 3 drives (figure around 550-600MB/s with Seagates or Toshiba). These are real world numbers (I'm doing it right now), and that's only for large writes. When disk & RAID card cache are used for smaller writes you're talking 4GB/s writes. The LSI card will allow you to force write-back even without a battery on the card, which some other RAID card manufacturers won't allow.
WD's are overrated IMO. Their price-to-performance (and quality) are lower than other drives out there. Seagates are some of the fastest and cheapest but have a high failure rate. Hitachis (HGST) cost more (except OEM bare drives), their performance is a little lower but they're very reliable. Toshibas fall pretty nicely in the middle. Their 2-4TB drives benchmark out of the box with the Seagates (upwards of 200MB/s read & write) and have good reliability (they actually own Hitachi & share manufacturing plants). In the RAID-5 in my home rig I use Seagates as my data is backed up anyway and I enjoy the performance. In the workstations I build professionally I use a lot of Toshibas and some Hitachis (mainly in large arrays when building servers).