Hey there, jek_748!
Unfortunately, what you want to do is literally impossible as Ijack mentioned. You can either do RAID 1 or RAID 0 with those 2 drives, but you cannot do both.
Before you buy the two 3 TB HDDs make sure they are the same identical drives.
Also it's advisable to put HDDs that are specifically designed for RAID systems like the WD Red drives. Such drives are tested in 24/7 environments and have a specific feature TLER (time-limited error recovery). With coordinated error handling, the hard drive is not dropped from the RAID array, thereby avoiding the entire RAID recovery, replacement, rebuild, and return experience.
Otherwise you are risking voiding the warranty of any other regular HDD in your system, plus higher possibility of failure.
So I guess what you need to decide is whether you want the reliability of RAID 1 or the speed of RAID 0 with the two HDDs.
You can have both in RAID 10 but you will need a minimum of 4 HDDs.
Hope this was helpful. Good luck!
SuperSoph_WD