There's no real 'sweet spot' for exact voltages / memory speeds to achieve from my experience. You simply need to test and trial it yourself.
Slowly bump up your memory speed in small increments, stop, test the stability of your system, if OK, repeat, until you hit a point that system stability is compromised, then just pull back to the last good settings.
You can eventually change voltages, but this is a different and more risky process entirely. You can view an entire guide on overclocking here: http://www.tomshardware.co.uk/forum/340404-33-wolfram-overclocking-guide