Ok, in the first picture, you have no rear exhaust fan. In the second picture you do...
I saw the 80mm side panel fan in your first picture.
Are there any front intake fans?
Sticking the GPU in the bottom slot like that is going to cause the GPU to heat up more. That heat needs to exit the case somewhere, and that location is the PSU fan and the open/occupied rear case fan. The heat is still going past the CPU area. Very little heat/airflow goes out the slotted expansion bracket of the GPU.
Turning your CPU heatsink so the fan points out the back of the case instead of up into the PSU is likely the best orientation.
The fact that having the side panel off doesn't improve CPU temps, but turning the case on its side tells me you've got a mounting pressure (or lack thereof) issue on the CPU heatsink. Maybe laying the case on its side allows the weight of the CPU heatsink to keep it fully seated atop the CPU. This needs to be investigated further.
Maybe you need to afford a new case? Can get something much better for $60 or less.
There is a front intake, a 120mm fan.
I tried moving the video card to the other slot, thanks its something i should've tried before. much better running temps from the GPU, idles at about 47c now, at least 5c better. i'll test it under load later.
Can't move the CPU cooler, the retention bracket only fits one way. I did remove the cooler to see if i could alter it, but its this way or nothing.
I have seen a Coolermaster CPU watercooler with a single fan/radiator, for about the same price as a case i was considering (CIT Dark Soul). Next month i should be able to hopefully afford one or the other.....I'll see how the testing goes until then.
Tanks again for the advice and insights