For a balanced build, you should optimize the setup to minimize the amount of work each fan has to do. This means using the H100i as a top exhaust, which gives up a few degrees, but will let the rest of the fans spin slower.
The best 120mm fan out there right now is the Corsair ML120 Pro. Use two of those for the H100i, and one on the rear.
Connect the two on the H100i to the H100i pump, as it has some safety features built in that require control of the fans.
For the rear fan, you'll need to change a setting on the motherboard before connecting the ML120 to it. Specifically, you need to make sure that CHA_FAN1 is set to PWM control. You do not want it set to either AUTO or DC control. Both can damage the fan.
For the front of the...